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Beschreibung

The characterisation of the most novel metallofullerenes up to 2004 has been theoretically and systematically discussed in this Ph-D thesis presented in 2005 at Universitat Rovira i Virgili and reissued in 2011. From the structural point of view, metallofullerenes can be divided into three main groups according to the metal position: endohedral, heterohedral and exohedral metallofullerenes. The main families of compounds studied are Sc3-nMnN@Ck (n = 0-3, M = Y, La; k = 68, 78, 80) for endohedrals, CxMn (x = 56, 57, 58, 59; M = Pt, Ir, Os; n = 1, 2) for heterohedrals and Ck-{M(PH3)2}n (k = 60, 70, 84; M = Pt, Pd, Ni; n = 1, 2, 4, 6) for exohedrals. The present research is a step forward in the knowledge of each of these families of compounds, and in particular, in our understanding of the metal-carbon bond, isomerism and reactivity. The DFT method proved to be an excellent computational tool for providing good geometries, for solving the intricacies of the different metal-carbon bonds, for reproducing experimental data (ionization potentials and electron affinities) and also for making predictions about isomerism stability and reactivity.

Mitwirkende

Autor Josep Maria Campanera Alsina

Produktdetails

DUIN 1A156A9OA6N

GTIN 9783846520376

Sprache Englisch

Seitenanzahl 236

Produkttyp Taschenbuch

Metallofullerenes

Structure, isomerism, reactivity and properties

Josep Maria Campanera Alsina

€ 67,73

Verkäufer: Dodax EU

Lieferdatum: zwischen Donnerstag, 26. Juli und Montag, 30. Juli

Zustand: Neu

inklusive MwSt. - GRATIS LIEFERUNG
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